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| SECTION 2 : HAZARD(S) IDENTIFICATION |
| Classification of the chemical in accordance with CFR 1910.1200(d)(f): |
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GHS Pictograms:
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| Signal Word: | DANGER. |
| GHS Class: |
Flammable Liquid. Category 2. Aspiration Hazard. Category 1. Skin Irritation. Category 2. |
| Hazard Statements: |
H225 - Highly flammable liquid and vapor. H304 - May be fatal if swallowed and enters airways. H315 - Causes skin irritation. |
| Precautionary Statements: |
P210 - Keep away from heat/sparks/open flames/hotsurfaces. — No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P264 - Wash hands thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302+P352 - IF ON SKIN: Wash with plenty of water. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P321 - Specific treatment (see ... on this label). P331 - Do not induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use dry chemical, carbon dioxide to extinguish small fires. Use water for large fires. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container in accordance with Local, State, Federal and Provincial regulations. |
| Hazards not otherwise classified that have been identified during the classification process: |
| Route of Exposure: | Eyes. Skin. Inhalation. Ingestion. |
| Potential Health Effects: | |
| Eye: | Can cause moderate irritation, burning sensation, tearing, redness, and swelling. Overexposure may cause lacrimation, conjunctivitis, corneal damage and permanent injury. |
| Skin: | Skin contact with the liquid may cause freezing of the skin or irritation |
| Inhalation: | Respiratory tract irritant. High concentration may cause dizziness, headache, and anesthetic effects. Inhalation of concentrations above the recommended limits may cause temporary central nervous system depression with anesthetic effects such as dizziness, headache, incoordination and loss of consciousness or temporary alteration of the heart’s electrical activity (cardiac arrhythmia). Gross overexposure may be fatal. |
| Ingestion: | Causes irritation, a burning sensation of the mouth, throat and gastrointestinal tract and abdominal pain. |
| Chronic Health Effects: | Prolonged skin contact may lead to burning associated with severe reddening, swelling, and possible tissue destruction. |
| Signs/Symptoms: | Overexposure can cause headaches, dizziness, nausea, and vomiting. |
| Target Organs: | Eyes. Skin. Respiratory system. Digestive system. |
| Aggravation of Pre-Existing Conditions: | Individuals with preexisting diseases of the central nervous or cardiovascular system may have increased susceptibility to the toxicity of excessive exposure |
| SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS |
| Mixtures: |
| Chemical Name | CAS# | Ingredient Percent | EC Num. |
| Petroleum Solvent | 64741-66-8 | 80 - 90 by weight | |
| Silicone Polymer Blend | No Data | 1 - 10 by weight | |
| SECTION 4 : FIRST AID MEASURES |
| Description of necessary measures: |
| Eye Contact: | Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention. |
| Skin Contact: | Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while removing contaminated clothing and shoes. Get medical attention if irritation develops or persists. |
| Inhalation: | If inhaled, remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. |
| Ingestion: | If swallowed, do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. |
| Most important symptoms/effects, acute and delayed: | |
| Other First Aid: | Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested. Provide a glass of water to dilute the material in the stomach. If vomiting occurs naturally, have the person lean forward to reduce the risk of aspiration. |
| Indication of immediate medical attention and special treatment needed: | |
| Note to Physicians: | Because of possible disturbance of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used only in situations of emergency life support |
| SECTION 5 : FIRE FIGHTING MEASURES |
| Suitable and unsuitable extinguishing media: | |
| Suitable Extinguishing Media: | Use carbon dioxide (CO2) or dry chemical when fighting fires involving this material. |
| Special protective equipment and precautions for fire-fighters: | |
| Protective Equipment: | As in any fire, wear Self-Contained Breathing Apparatus (SCBA), MSHA/NIOSH (approved or equivalent) and full protective gear. |
| Fire Fighting Instructions: |
Evacuate area of unprotected personnel. Use cold water spray to cool fire exposed containers to minimize risk of rupture. Do not enter confined fire space without full protective gear. If possible, contain fire run-off water. Vapors can flow along surfaces to distant ignition sources and flash back. |
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| SECTION 6 : ACCIDENTAL RELEASE MEASURES |
| Personal precautions, protective equipment and emergency procedures: | |
| Personal Precautions: | Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. |
| Environmental precautions: | |
| Environmental Precautions: | Avoid runoff into storm sewers, ditches, and waterways. |
| Methods and materials for containment and cleaning up: | |
| Spill Cleanup Measures: |
Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical waste container. Provide ventilation. Collect spill with a non-sparking tool. Place into a suitable container for disposal. Clean up spills immediately observing precautions in the protective equipment section. After removal, flush spill area with soap and water to remove trace residue. Flammable, eliminate ignition sources. Vapors can form an ignitable mixture with air. Vapors can flow along surfaces to distant ignition sources and flash back. Ventilate area. Use proper personal protective equipment as listed in Section 8. |
| Reference to other sections: | |
| Other Precautions: | Pump or shovel to storage/salvage vessels. |
| SECTION 7 : HANDLING and STORAGE |
| Precautions for safe handling: | |
| Handling: | Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Material will accumulate static charges which may cause an electrical spark (ignition source). Use proper grounding procedures. Do not reuse containers without proper cleaning or reconditioning. |
| Hygiene Practices: | Wash thoroughly after handling. |
| Special Handling Procedures: | Hazardous liquid or vapor residue may remain in emptied container. Do not reuse, heat, burn, pressurize, cut, weld, braze, solder, drill, grind, expose to sparks, flame, or ignition sources of empty containers without proper commercial cleaning or reconditioning. |
| Conditions for safe storage, including any incompatibilities: | |
| Storage: | Store in a cool, dry, well ventilated area away from sources of heat, combustible materials, direct sunlight, and incompatible substances. Keep container tightly closed when not in use. |
| SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION |
| EXPOSURE GUIDELINES: |
| Appropriate engineering controls: |
| Engineering Controls: | Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficient to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment. |
| Individual protection measures: | |
| Eye/Face Protection: | Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face protection regulation, or the European standard EN 166. |
| Skin Protection Description: | Wear appropriate protective gloves and other protective apparel to prevent skin contact. Consult manufacturer's data for permeability data. |
| Respiratory Protection: | A NIOSH approved air-purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. |
| Other Protective: | Facilities storing or utilizing this material should be equipped with an eyewash and a deluge shower safety station. |
| General Hygiene Considerations: | Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before eating, drinking, smoking, using the toilet, or applying cosmetics |
| Notes : | Only established PEL and TLV values for the ingredients are listed. |
| SECTION 9 : PHYSICAL and CHEMICAL PROPERTIES |
| PHYSICAL AND CHEMICAL PROPERTIES: |
| Physical State Appearance: | Liquid. |
| Color: | Clear |
| Odor: | Slight ethereal. |
| Boiling Point: | 205-255°F (96.1-123.8°C) |
| Melting Point: | Not determined. |
| Specific Gravity: | 0.72 |
| Solubility: | Insoluble. |
| Vapor Density: | 4 (air = 1) |
| Vapor Pressure: | 63 mmHg @68°F |
| Percent Volatile: | Not determined. |
| Evaporation Rate: | 5.6 (butyl acetate = 1) |
| pH: | Not determined. |
| Molecular Formula: | Mixture |
| Molecular Weight: | Mixture |
| Flash Point: | >19°F (-7.2°C) |
| Flash Point Method: | Tag closed cup. (TCC) |
| Lower Flammable/Explosive Limit: | 1.5 % (Approximately) |
| Upper Flammable/Explosive Limit: | 11.6% |
| Auto Ignition Temperature: | 750°F |
| VOC Content: | Not determined. |
| 9.2. Other information: |
| Percent Solids by Weight | Not determined. |
| SECTION 10 : STABILITY and REACTIVITY |
| Chemical Stability: | |
| Chemical Stability: | Stable under normal temperatures and pressures. |
| Possibility of hazardous reactions: | |
| Hazardous Polymerization: | Not reported. |
| Conditions To Avoid: | |
| Conditions to Avoid: | Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and oxidizing conditions. |
| Incompatible Materials: | |
| Incompatible Materials: | Oxidizing agents. Strong acids and alkalis. |
| Hazardous Decomposition Products: | |
| Special Decomposition Products: | Thermal oxidative decomposition can produce, silicone dioxide, carbon oxides and traces of incompletely burned carbon compounds and formaldehyde |
| SECTION 11 : TOXICOLOGICAL INFORMATION |
| TOXICOLOGICAL INFORMATION: |
| Petroleum Solvent : | |
| Eye: | Skin Rabbit LD50: > 2000 mg/kg (ECHA) |
| Inhalation: | Inhalation Rat LC50: > 5610 mg/m³/4 h (ECHA) |
| Ingestion: | Ingestion Rat LD50: > 5000 mg/kg (ECHA) |
| SECTION 12 : ECOLOGICAL INFORMATION |
| Ecotoxicity: | |
| Ecotoxicity: | No ecotoxicity data was found for the product. |
| Environmental Fate: | No environmental information found for this product. |
| SECTION 13 : DISPOSAL CONSIDERATIONS |
| Description of waste: |
| Waste Disposal: | Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines. |
| RCRA Number: | D001 |
| Important Disposal Information: | DANGER! Rags, steel wool and waste soaked with this product may spontaneously catch fire if improperly discarded or stored. To avoid a spontaneous combustion fire, immediately after use, place rags, steel wool or waste in a sealed, water-filled, metal container. |
| SECTION 14 : TRANSPORT INFORMATION |
| DOT Shipping Name: | Refer to Bill of Lading |
| DOT UN Number: | Refer to Bill of Lading |
| SECTION 15 : REGULATORY INFORMATION |
| Safety, health and environmental regulations specific for the product: |
| Petroleum Solvent : | |
| TSCA Inventory Status: | Listed |
| Canada DSL: | Listed |
| Canadian Regulations. | WHMIS Hazard Class(es): B2; D2B All components of this product are on the Canadian Domestic Substances List. |
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WHMIS Pictograms:
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| SECTION 16 : ADDITIONAL INFORMATION |
| HMIS Ratings: | |||||||||||||||||
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| SDS Revision Date: | September 10, 2015 |
| MSDS Revision Notes: | "GHS Update" |
| SDS Format: | In accordance to OSHA GHS 1910.1200 |
| MSDS Author: | Actio Corporation |
| Disclaimer: | This Health and Safety Information is correct to the best of our knowledge and belief at the date of its publication but we cannot accept liability for any loss, injury or damage which may result from its use. The information given in the Data Sheet is designed only as a guidance for safe handling, storage and the use of the substance. It is not a specification nor does it guarantee any specific properties. All chemicals should be handled only by competent personnel, within a controlled environment. |
